Insight into the strong aggregation-induced emission of low-conjugated racemic C6-unsubstituted tetrahydropyrimidines through crystal-structure–property relationship of polymorphs† †Electronic supplementary information (ESI) available: General method, instruments, preparation of polymorphs, characterization data, 1H and 13C NMR of THP 3, Table S1 and S2, Fig. S1–S4, “cif” files containing single-crystal X-ray diffraction data of 2c, 2c', 3p, 3b and 3c. CCDC 850811, 1011037–1011040. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc01226k Click here for additional data file. Click here for additional data file.

Isolation, structure and reactivity of a scandium boryl oxycarbene complex† †Electronic supplementary information (ESI) available: Synthesis, characterization of compounds 2 – 7. CCDC 981561–981563, 1042268 and 1042269. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc03138a Click here for additional data file. Click here for additional data file.

Experimental Section S3 Synthesis and Characterization of Scandium Boryl Carbene Complex (2) S4 Synthesis and Characterization of Phenylamido Enolate Complex (3) S4 13C-Labeled Experiments for Complex 3 S5 Synthesis and Characterization of Scandium Alkoxide Complex (4) S5 Synthesis and Characterization of Scandium Pyridyl Complex (5) S6 Figure S1. ORTEP drawings of 5 S6 Synthesis and Characteri...

Homochiral self-assembly of biocoordination polymers: anion-triggered helicity and absolute configuration inversion† †Electronic supplementary information (ESI) available: Preparation and physical characterization data of 1P and 2M, additional structural description, UV-Vis and CD spectra (Fig. S1–S7), crystallographic refinement details for 1P and 2M (Table S1), selected bond distances and angles for 1P and 2M (Tables S2–S5), ESI(+)-MS and ESI(+)-MSMS spectra (Fig. S8–S11 and Schemes S1 and S2) and PXRD (Fig. S12). CCDC 1046609 and 1046610. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc01089f Click here for additional data file. Click here for additional data file.

Hydrogen bonding vs. halogen bonding: the solvent decides† †Electronic supplementary information (ESI) available: Full details of all experimental procedures and analysis of NMR spectroscopic data, powder X-ray data and single-crystal X-ray diffraction data. CCDC 1478819 and 1478820, for compounds 2b·3 and 2c·3 contain the supplementary crystallographic data for this paper. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc01801k Click here for additional data file. Click here for additional data file.

Department of Chemistry, University of She E-mail: [email protected] Department of Chemistry, University of Y E-mail: [email protected] Department of Chemistry, University of Ca 1EW, UK. E-mail: [email protected] † Electronic supplementary information experimental procedures and analysis of data and single-crystal X-ray diffraction compounds 2b$3 and 2c$3 contain the s this paper....

The protecting-group free selective 3′-functionalization of nucleosides† †Electronic supplementary information (ESI) available. CCDC 1525736–1525737. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc05081f Click here for additional data file. Click here for additional data file.

General ............................................................................................................................................S1 General Procedure A: Preparation of 3’-Phosphorylated Nucleosides .................................S1 Preparation of 3’-acetylated Nucleosides...................................................................................S8 NMR Studies .........

An ambient stable core-substituted perylene bisimide dianion: isolation and single crystal structure analysis† †Electronic supplementary information (ESI) available: Synthesis, spectroelectrochemistry, UV-vis, electrochemistry, X-ray diffraction, NMR and mass spectra. CCDC 1032959. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc03671a Click here for additional data file. Click here for additional data file.